S,S-dimethyl sulfoximine

CAS number: 1520-31-6

Molecular formula:

molecular weight:

Chemical structure:

English name: S, S-dimethylsulfoximine
English synonyms: S, S-dimethylsulfoximine; DiMethylsulfoxiMide; Dimethylsulfoximine; S,S-Dimethylsulfoximide; Sulfoximine,S,S-dimethyl-(7CI,8CI,9CI); S,S-Dimethylsulphoximine98%; (Dimethanesulfinylidene)amine; (S-Methylsulphonimidoyl)methane
CAS No.: 1520-31-6
Molecular formula: C2H7NOS
Molecular weight: 93.15
Relevant category: spot; Synthetic material intermediates;
2018Mol file: 1520-31-6.mol

Properties of dimethyl sulfimide
Melting point 56 ° C
Boiling point 105 ºC
Density 1.13
Flash point 18 ºC
Storage conditions Keepinmarkplace, Inertatmosphere, Storeinreezer, under-20 ° C
Form powdertocrystal
Color WhitetoAlmostwhite

Brief introduction to the use and synthesis method of dimethyl sulfimide

Dimethylsulfinylimide is an organic intermediate, which can be obtained by the reaction of dimethyl sulfoxide with ammonium carbamate under the catalysis of PhI (OAc) 2. Preparation: add dimethyl sulfoxide (1.0g, 12.8mmol) into methanol (50ml), and then add PhI (OAc) 2 (12.4g, 38.4mmol) and ammonium carbamate (4.0g, 51.2mmol). Stir at room temperature for 1 hour. After the reaction is complete, it is concentrated, and the residue is separated by column chromatography (eluent: dichloromethane/methanol) to obtain the compound dimethyl sulfimide (1.01g, yield: 85%).